2-(2-Chlorophenoxy)acetohydrazide
نویسندگان
چکیده
In the title compound, C(8)H(9)ClN(2)O(2), the acetohydrazide group is approximately planar, with the maximum deviation of 0.031 (2) Å. In the crystal, the mol-ecules are linked by N-H⋯N, N-H⋯O and C-H⋯O hydrogen bonds, with the acetohydrazide O atom accepting two C-H⋯O links and one N-H⋯O link. This results in infinite sheets lying parallel to (100).
منابع مشابه
2-(4-Chlorophenoxy)-N′-[2-(4-chlorophenoxy)acetyl]acetohydrazide monohydrate
In the title compound, C(16)H(14)Cl(2)N(2)O(4)·H(2)O, the hydrazine and water mol-ecules are both located on twofold axes. The C-N-N-C torsion angle is -72.66 (1)° and the dihedral angle between the two benzene rings is 67.33 (1)°. In the crystal, mol-ecules are linked into a layer structure by a combination of O-H⋯O, N-H⋯O and C-H⋯O hydrogen bonds. Adjacent layers are linked into a three-dimen...
متن کامل2-(4-Chlorophenoxy)acetohydrazide
In the title compound, C(8)H(9)ClN(2)O(2), the two planar fragments, i.e. the chloro-phenyl and C-C(=O)-N groups, are inclined at 14.93 (17)°. In the crystal, relatively weak inter-molecular N-H⋯N, C-H⋯O and N-H⋯O hydrogen bonds connect the mol-ecules into layers. The hydro-phobic parts of mol-ecules stick outside these layers and are connected with the neighbouring layers only by van der Waals...
متن کامل(E)-2-(4-Chlorophenoxy)-N′-(pyridin-4-ylmethylidene)acetohydrazide
In the title compound, C14H12ClN3O2, the acyl-hydrazone base [C(=O)-N-N=C] is essentially planar, with an r.m.s. deviation of 0.0095 Å, and makes a dihedral angle of 12.52 (10)°with the pyridine ring. In the crystal, molecules are linked via pairs of N-H⋯O hydrogen bonds, forming inversion dimers with an R2(2)(8) graph-set motif. The dimers are linked via C-H⋯π interactions forming chains along...
متن کاملN′-(2-Fluorobenzylidene)acetohydrazide
The title compound, C(9)H(9)FN(2)O, was prepared by the reaction between 2-fluoro-benzophenone and acetohydrazide. In the crystal structure, inversion dimers linked by pairs of N-H⋯O hydrogen bonds occur, generating R(2) (2)(8) loops.
متن کامل(E)-N′-[1-(2-Hydroxyphenyl)ethylidene]-2-phenoxyacetohydrazide–2,2′-(1,1′-azinodiethylidyne)diphenol (2/1)
The formula unit of the title mol-ecular complex, 2C(16)H(16)N(2)O(3)·C(16)H(16)N(2)O(2), consists of two (E)-N'-[1-(2-hy-droxy-phen-yl)ethyl-idene]-2-phen-oxy-acetohydrazide mol-ecules and one mol-ecule of 2,2'-(1,1'-azinodiethyl-idyne)diphenol, with the latter located on a crystallographic inversion center. The acetohydrazide mol-ecules are linked into a supermolecular chain along the c axis ...
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